"It has been reported that single-site catalysts have limitations for reactions involving large molecules due to the lack of surrounding ensemble sites to accommodate the molecule and its products. However, our results show that the single-site Pt1/CeO2 is 309 times more active than Pt particles supported on CeO2 or Al2O3"

"The first-order model involving only one reactant is unsuitable since the correlative coefficient (R2) of each step is not high enough as seen in Fig. S10 (SI), suggesting that the kinetics of these reactions is not explainable by a simple power-law empirical model"

"This discrepancy underscores that conclusions drawn solely from Pt (111) studies risk overestimating catalyst robustness, highlighting the importance of bridging model-surface insights with nanoparticle- and support-level realities to accurately evaluate the stability and selectivity in practical MCH dehydrogenation."

"Earlier it was thought that since the chemical storage method is nonreversible, the compounds cannot be used in cycles. In view of this supply of hydrogen through liquid organic hydrides (LOH) using catalytic reaction pair of dehydrogenation of cycloalkanes such as methylcyclohexane, cyclohexane and decalin; and hydrogenation of corresponding aromatics is a useful process for supply of hydrogen to PEMFC."

"Another computational study considered LOHCs with heteroatoms, suggesting that ethanolamine is not as stable as was previously assumed; thus, dehydrogenative coupling of 2-aminoethanol to form 2,5-piperazinedione has a lower reaction enthalpy than H12-NEC dehydrogenation."

"These results are significant since the dehydrogenation reactions had previously been reported to be very slow with no selectivity to the completely dehydrogenated product, N-ethylcarbazole."